Miranda Lambert performed "Gunpowder & Lead" during a period when she was solidifying her status as a leading figure in country music. The song is from her second studio album, "Crazy Ex-Girlfriend," released in 2007. By the time of this live recording, Lambert had already gained significant acclaim, including her first Grammy nomination. "Gunpowder & Lead" became one of her signature tracks, showcasing her strong vocal style and storytelling ability, which resonated with audiences. At this point in her career, she was known for her fierce independence in both her lyrics and public persona, establishing her as a trailblazer for women in country music. The live recording highlights her electrifying stage presence, which has played a key role in her enduring popularity.